@article {ZHANG2022138082,
	title = {Immobilized N-C/Co derived from ZIF-67 as PS-AOP catalyst for effective tetracycline matrix elimination: From batch to continuous process},
	journal = {Chemical Engineering Journal},
	volume = {450},
	year = {2022},
	pages = {138082},
	abstract = {The successful preparation of immobilized nitrogen-doped carbon/cobalt @ porous spherical substrate (N-C/Co@PSS) catalyst derived from ZIF-67 was reported in this work. The oxytetracycline (OTC), tetracycline (TTC), and chlortetracycline (CTC) in the simulated wastewater were decomposed via the peroxymonosulfate (PMS) activation by N-C/Co@PSS. The degradation of TCs was initially investigated by batch-type experiments, in which ca. 100\% TCs with an initial concentration of 10.0~mg L-1 can be degraded over N-C/Co@PSS~+~PMS system within 15~min for 30 runs{\textquoteright} operation. In addition, detailed non-radical dominating degradation mechanism was explored by active species capture experiments, electron spin resonance (ESR) tests and electrochemical technology. Furthermore, continuous degradation of TCs antibiotics for up to 200~h in the packed N-C/Co@PSS fixed bed reactors could be accomplished. This work provides theoretical and technical support for the application of MOFs-based catalysts in large-scale wastewater remediation.},
	keywords = {Advanced oxidation processes, Derivatization, immobilization, Wastewater remediation, ZIF-67},
	issn = {1385-8947},
	doi = {http://doi.org/10.1016/j.cej.2022.138082},
	url = {http://www.sciencedirect.com/science/article/pii/S1385894722035689},
	author = {Xiu-Wu Zhang and Ming-Yan Lan and Fei Wang and Chong-Chen Wang and Peng Wang and Chengjun Ge and Liu, Wen}
}