@article {doi:10.1021/acsami.0c03481,
	title = {Novel CuCo2O4 Composite Spinel with a Meso-Macroporous Nanosheet Structure for Sulfate Radical Formation and Benzophenone-4 Degradation: Interface Reaction, Degradation Pathway, and DFT Calculation},
	journal = {ACS Applied Materials \& Interfaces},
	volume = {12},
	number = {18},
	year = {2020},
	note = {PMID: 32271545},
	pages = {20522-20535},
	abstract = {A series of CuCo2O4 composite spinels with an interconnected meso-macroporous nanosheet morphology were synthesized using the hydrothermal method and subsequent calcination treatment to activate peroxymonosulfate (PMS) for benzophenone-4 (BP-4) degradation. As-prepared CuCo2O4 composite spinels, especially CuCo-H3 prepared by adding cetyltrimethylammonium bromide, showed superior reactivity for PMS activation. In a typical reaction, BP-4 (10.0 mg/L) was almost completely degraded in 15 min by the activation of PMS (200.0 mg/L) using CuCo-H3 (100.0 mg/L), with only 9.2 μg/L cobalt leaching detected. Even after being used six times, the performance was not influenced by the lower leaching of ions and surface-absorbed intermediates. The possible interface mechanism of PMS activation by CuCo-H3 was proposed, wherein a unique interconnected meso-macroporous nanosheet structure, strong interactions between copper and cobalt, and cycling of Co(II)/Co(III) and Cu(I)/Cu(II) effectively facilitated PMS activation to generate SO4{\textbullet}{\textendash} and {\textbullet}OH, which contributed to BP-4 degradation. Furthermore, combined with intermediates detected by liquid chromatography quadrupole time-of-flight mass spectrometry and density functional theory calculation results, the degradation pathway of BP-4 involving hydroxylation and C{\textendash}C bond cleavage was proposed.},
	doi = {10.1021/acsami.0c03481},
	url = {http://doi.org/10.1021/acsami.0c03481},
	author = {Yiping Wang and Ji, Haodong and Liu, Wen and Xue, Tianshan and Liu, Chao and Yuting Zhang and Liu, Longyan and Qiang Wang and Fei Qi and Bingbing Xu and Tsang, Daniel C. W. and Chu, Wei}
}